DOSEN PROFIL LENGKAP

Dithiolene metal complexes are complexes containing 1,2-dithiolene ligands. 1,2-Dithiolene ligands, a particular case of 1,2-dichalcogenolene species along...

absorption at 855 nm. The complex is a prototype of a large family of bis(dithiolene) complexes or the formula Ni(S2C2R2)2 (R = H, alkyl, aryl). These complexes...

can also be found in coordination chemistry, for example among bis(1,2-dithiolene) metal complexes. Diradicals are usually triplets. The phrases singlet...

((CH(CN))2). Maleonitriledithiolate is often abbreviated mnt. It is a "dithiolene", i.e. a chelating alkene-1,2-dithiolate. It is a prototypical non-innocent...

the 4,5-bis(sulfanyl)-1,3-dithiole-2-thione. The salt is a precursor to dithiolene complexes and tetrathiafulvalenes. Reduction of carbon disulfide with...

Johnson, M. K.; Schaefer, H. F. III; and Robinson, G. H., “A Stable Anionic Dithiolene Radical”, Journal of the American Chemical Society. 2017, 139, 6859–6862...

their active sites. In the case of DMSOR, the Mo center is found to two dithiolene provided by two pyranopterin cofactors. These organic cofactors, called...

example of a near-IR photodetector based on neutral [M(R-dmet)2] bis(1,2-dithiolene) metal complexes". Inorganic Chemistry Communications. 10 (2): 191–194...

Arca, Massimiliano (May 2017). "[Au(pyb-H)(mnt)]: A novel gold(III) 1,2-dithiolene cyclometalated complex with antimicrobial activity (pyb-H=C-deprotonated...

four thiolate-like ligands provided by the two dithiolene cofactors, the molybdopterins. The dithiolene and cysteinyl/selenocysteinyl ligands are redox-innocent...

2-dithiolates, called dithiolene complexes, are well known. Karlin, K. D.; Stiefel, E. I., Eds. “Progress in Inorganic Chemistry, Dithiolene Chemistry: Synthesis...

illustrated by nickel bis(stilbenedithiolate) ([Ni(S2C2Ph2)2]z). As all bis(1,2-dithiolene) complexes of nd8 metal ions, three oxidation states can be identified:...

In the following step, MPT synthase catalyzes the incorporation of the dithiolene moiety  to precursor Z, which converts it to molybdopterin. More specifically...

2-dithietes have been isolated; one (low-yielding) route is oxidation of a dithiolene complex. Computation suggests that electron-donating substituents tend...

Seifert, Gotthard; Feng, Xinliang (2017). "Immobilizing Molecular Metal Dithiolene–Diamine Complexes on 2D Metal–Organic Frameworks for Electrocatalytic...

Richard; Gray, Harry B. (2011-10-17). "Noninnocence in Metal Complexes: A Dithiolene Dawn". Inorganic Chemistry. 50 (20): 9741–9751. doi:10.1021/ic2011748...

oxidized state, molybdenum is coordinated by a cysteine thiolate, the dithiolene group of molybdopterin, and two terminal oxygen atoms (oxos). Upon reacting...

early classes of such materials are based on substituted ferrocenes and dithiolene complexes; more recent work shows that alkoxystilbazoles have similar...

Lipscomb and his students. Among these are hydrazine, nitric oxide, metal-dithiolene complexes, methyl ethylene phosphate, mercury amides, (NO)2, crystalline...

Fe(S2CNEt2)2(phen). 3,4-Bis(trifluoromethyl)-1,2-dithiete reacts to give the Fe(IV) dithiolene complex Fe(S2CNEt2)2(S2C2(CF3)2). Nitric oxide and carbon monoxide add...

+ 2 Cl− Enedithiolates displace all four chloride ligands to give bis(dithiolene) complexes. Reduction gives colloidal platinum of potential interest for...

metal complexes are a class of coordination compounds homologous to 1,2-dithiolene metal complexes and formally deriving from ene-1,2-diselenolato ligands...

higher temperature back to the dithiete. It is used to prepare metal dithiolene complexes. It reacts with low valent metal complexes by oxidative addition:...

distorted square pyramidal geometry bound an oxo/hydroxo ligand and the dithiolene substituents of two molybdopterin cofactors. Two molybdopterin cofactors...

a redox-active tungsten. The tungsten in FwdBD is coordinated by four dithiolene thiolates. Six sulfurs from the thiolate of Cys118 and an organic sulfide...

name 3H-1,2-Dithiole Other names 1,2-Dithiacyclopentene 1,2-Dithiole 1,2-Dithiolene Identifiers CAS Number 288-26-6 Y 3D model (JSmol) Interactive image ChemSpider...

molybdopterin-containing enzymes are based on a class of ligands known as dithiolenes. Some bacterial oxidoreductases use tungsten in a similar manner as molybdenum...

3-propanedithiol. Unsaturated versions of 1,2-dithiolates usually take the form of dithiolene ligands, the parent member being (HC)2S2−2. Metal thiolate complexes are...

1,2-diimine. 1,2-Diketimines are “non-innocent ligands”, akin to the dithiolenes. For example, acetylacetone (2,4-pentanedione) and a primary alkyl- or...